Volume 8 Number 12 Subjects Discussed In This Issue: Tekhelet [Baruch Sterman] ---------------------------------------------------------------------- From: Baruch Sterman <baruch@...> Date: Tue, 29 Jun 93 22:38:10 EDT Subject: Tekhelet I noticed that there has been some discussion of late on the net regarding the issue of Tekhelet. I have been involved with this for the past two years, specifically with Trunculus Tekhelet. I wrote this article which is a general introduction to the history of the subject - but not totally rigorous from the Halachik side. We are at the stage where within a few months we will have enough Tekhelet to begin selling strings to interested parties. Anyone who would like to find out more details, please feel free to reach me at: Baruch Sterman Te'ena Mizrach 76 Efrat, Israel 972-2-932-136 <baruch@...> The Riddle of the Biblical Blue or The Quest for the Holy Snail Baruch Sterman The story of the rediscovery of the source for the dye tek- helet - Biblical Blue, is one of intrigue, deception, deduc- tion, and luck. It weaves together clues from archeology, chemistry and Biblical scholarship and its major players in- clude Jewish and Non-Jewish archeologists, marine biologists and chemists, the leader of a Hasidic sect, and the former Chief Rabbi of Israel. The book of Numbers records, "And God spoke to Moses saying, Speak to the Children of Israel and say unto them, that they shall make for themselves fringes on the corners of their garments for their generations, And they shall place on the corner fringes a thread of blue. And they shall see it and remember all of my commandments." In ancient times colored dyes were rare and valuable, and the most prized of all were the purple and blue derived from mollusks, literally worth their weight in gold. Porphyra in Greek originally meant shellfish and the word purple applied to the range of colors from purple to blue which were of shellfish origin. These precious dyes were reserved for royalty; they colored the robes of the kings and princes of Media, Babylon, Egypt and Greece, and to wear them was to identify with the nobility. To the Greeks it was a sign of hubris as Agamemnon realizes when his wife Clytaemnestra convinces him to walk over the garments of the Gods, "Now since my will was bent to listen to you in this, my feet crush purple as I pass within the hall." The thread of blue on the corners of the Israelites' garments would have been conspicuous and solicited attention. The association with royalty reminded the Israelite of his duties towards his master, the King of the Universe -"And you shall be to me a kingdom of Priests". The Mediterranean coast was the center of the purple dyeing industry in the ancient world. Tyrian purple came from the port of Tyre in what is now southern Lebanon. The Talmud records that the hilazon - the mollusk source of the blue dye was to be found "from the ladders of Tyre to Haifa." The Phoenicians (the etymology of their name is from the word purple) made their wealth trading in the dyestuff, and dye houses were ubiquitous in the region. Because of its lucra- tive nature, purple dying slowly came under imperial con- trol. The Romans issued edicts that only royalty could wear purple garments and only imperial dye houses were permitted to manufacture the material. This drove the Jewish tekhelet making industry underground. A story is recorded in the Tal- mud of two students carrying tekhelet from Palestine to the Jews in Babylon, who were caught by the eagle (a Talmudic metaphor for Rome) and miraculously escaped death. With the Arab conquest of Palestine (683 AD.) the secret of tekhelet was lost. Purple dying continued to survive sporadically, with a small industry in Constantinople, until that city fell to the Turks on May 29, 1453. Jews continued to wear fringes on their garments but as the Midrash (circa 750 AD) laments, "and now we have no tek- helet, only white, for the tekhelet has been hidden." The description of the hilazon was recorded by the Talmud in various, often contradictory, passages. Its distinguishing features, were that it had a shell, it could be found along the northern coast of Palestine, and that its body was similar to the sea. The main characteristics of the tek- helet were its color, which was similar to the sky and sea, the steadfast nature of the dye, that it had to be taken from the hilazon while still alive, and that it was in- distinguishable from the counterfeit dye of vegetable origin, kala ilan - indigo. The rediscovery of the purple dye was due to a chance en- counter in 1858. The French zoologist Henri de Lacaze- Duthiers was on a scientific study sailing from the Minorcan port of Mahon when one of the fishermen took a snail, broke it open and smeared it on his shirt. He boasted that the yellow stain would soon turn red in the sunlight, and Lacaze-Duthiers immediately recognized the snail - Thais Haemastoma - as the long lost source of the ancient purple. Subsequent investigation by Lacaze-Duthiers revealed three mollusks in the Mediterranean which produced dyes, Thais Haemastoma and Murex Brandaris, which give a pure purple and Murex Trunculus, which yields a mixture of purple and blue. At the turn of the century P. Friedlander, a German chemist, conducted extensive research into the chemical nature of the purple dye and established the molecule as dibromoindigo, and the great Egyptologist, A. Dedekind, concluded that the source of ancient tekhelet was certainly Murex Trunculus. In 1887, utterly unaware of Lacaze-Duthiers' work, Gershon Henokh Leiner, a Hasidic Rebbe from the Russian-Polish town of Radzin, wrote a small pamphlet announcing that he was to begin searching for the lost hilazon in an effort to bring back the tekhelet to the Jewish people. Leiner was an excep- tional individual who might have been an engineer in a dif- ferent incarnation. With no formal secular training, he nevertheless spoke several European languages and taught himself mechanics and medicine. After he suceeded his father as leader of the Ishbitzer Hasidic sect, he established a mill furnished with machinery of his own design, which turned out an amazing 80,000 lbs. of flour daily. (The venture, however, eventually failed and brought Leiner and some of his Hasidim to complete financial ruin.) He set off (in cognito) to scour Europe and records that his travels brought him to Naples in Italy, where he saw "a great building of stone deep in the ground on the Mediter- ranean sea shore, with rooms built of white glass with sea water flowing through them. And in them all the sea crea- tures travel freely." Leiner concluded that the cuttlefish, Sepia officinalis, a type of squid, fit the description of the coveted hilazon. The only problem was that he could not fabricate a blue dye from the black ink that the squid released. He put an advertisement in the local paper of- fering a substantial reward to any chemist who could solve the problem. Eventually a solution was procured and Leiner went back to Radzin and opened up a factory to produce the tekhelet. Within two years, ten thousand of his followers were wearing the blue threads on their fringes. Leiner published two books to counter the strong opposition from other Rabbis who were not convinced that this was indeed the true hilazon. Nevertheless, the split between his followers and others who would not wear his tekhelet, ran deep and divisive, to the point where Radzin Hasidim were often not allowed into regular Jewish ritual baths, and the question arose as to whether they should be buried in regular Jewish cemeteries! In 1913, then Chief Rabbi of Ireland Rabbi Isaac Herzog (later Chief Rabbi of Israel and father of the President of Israel, Chaim Herzog) wrote a doctoral dissertation on the subject of Hebrew Porphyrology (the study of purple - a word Herzog coined). He requested a sample of their tekhelet from the Hasidim of Radzin, and then sent it off to leading chemists and dye experts in England and on the Continent. The results were unanimous; the dye was not organic - it was Prussian Blue, or Ferric Ferrocyanide! Herzog was sure that the source of the dye was Sepia, refusing to believe that Leiner would purposely mislead his followers. He asked the Radziners to send him the process that they used to make the dye and together with chemists, carefully studied it. The ink from the squid was mixed "with iron filings and a snow white chemical called Potasz. After keeping it on a large powerful fire for some four or five hours until the flames burn outside and inside as the fires of Hell the mix- ture fuses..." Since all the chemicals added were colorless, the dye master from Radzin was convinced that the blue color must come from the squid ink (as Leiner himself must have been). In fact, at that high temperature, the organic molecules dissociate and the nitrogen and carbon form inor- ganic cyanide - which mixed with the iron gave Prussian Blue. Leiner had been duped by some unscrupulous Italian chemist. Herzog could not accept the fact that genuine tekhelet depended on the hilazon in such a superficial manner, when in fact virtually any organic material - blood or corned beef for example - could be processed in the same way and yield the same dye. He thus discounted the Radzin tekhelet and sought an alternative. (As an interesting side note of history, during World War II with the destruction of East European Jewry, the tekhelet factories of Radzin were ruined and the process lost. When the survivors of Radzin made their way to Israel after the war, they asked Rabbi Herzog for the correspondence between himself and the Radzin dye makers, and through those letters reestablished a tekhelet industry in Israel which still flourishes to this day. Thus Herzog is responsible both for discrediting Radzin's tek- helet and at the same time for rescuing their process from destruction.) Herzog was aware of the strong evidence for associating one of the Murex species (Trunculus) with the hilazon. He knew of Lacaze-Duthiers' and Friedlander's work. He had read Pliny and Aristotle who indicated Brandaris and Trunculus as the source of the ancient purple dyes. He also knew of the archeological finds in Tyre and elsewhere which had un- covered mounds of millions of Murex shells broken in the exact spot necessary to obtain the dyestuff. Yet he could not bring himself to unequivocally identify Trunculus as the source of tekhelet for two reasons. Firstly, Murex Trun- culus, also known as the banded rock Murex, has stripes of brown against an off-white shell, hardly fitting the description of the Talmud as domeh l'yam - similar to the sea. Furthermore, the dye obtained from Trunculus is purplish-blue, not pure blue as tradition had maintained. Herzog proposed an alternative snail, Janthina, which has a violet shell and produces a bluish liquid when stimulated, though he never actually dyed with it. There are a number of difficulties with the identification of the hilazon with Janthina. The snail lives in the heart of the ocean in floating colonies and washes up on shore very rarely, which would make the snail so scarce as to be unattainable. It would also mean that the tekhelet used by the ancient Is- raelites was different than the blue dye the rest of the world used, and that neither Pliny nor Aristotle knew of it. But the main objection to Janthina is that it does not dye well. The blue-violet color of the dye turns to black- brown after a few days, and the dye is water soluble, hardly the steadfast blue of true tekhelet. All the evidence points in favor of Murex Trunculus, but what of Rabbi Herzog's objections? As for the first, that it is not similar to the sea, Herzog only saw specimens from the British Museum, after they had been cleaned and polished. In its natural state, however, Trunculus is covered with a coat of sea fouling which has a blue-green tint. Furthermore, since everything in the vicinity is covered with the same fouling, it is almost impossible to distinguish between a Trunculus shell and a neighboring rock. In Biblical Hebrew, yam can mean either sea or sea- bed. The Talmud may have meant that the hilazon is similar to the sea-bed, an exact description of Trunculus in situ. A short explanation of the chemical nature and origin of the dye molecules is required to understand the solution to Herzog's second objection, that the dye is not blue. Inside the hypobranchial gland, only the precursors to the dye exist as a clear liquid. (The indigo molecule contains a substance called indole, which is also found in the in- testines of animals, where it is a waste product of the proteins which constitute most of meat. Indole is a poison and does not pass out of the body directly. In order to get rid of it, animals unite it with sulphur, and this harmless combination is excreted through the kidney. In the snail, in addition to the sulphur, bromine and potassium are also in- corporated into the neutralized molecule.) When these are exposed to air and sunlight in the presence of an enzyme purpurase which also exists within the gland, they turn into the dye material. Purpurase quickly decomposes, so in order for this reaction to take place, the gland must be smashed soon after being taken from the live snail, in accordance with the Talmudic passage that the tekhelet is taken from the hilazon while still alive. In Haemastoma and Brandaris only dibromoindigo - Tyrian Purple - is produced, while in Trunculus this process yields monobromoindigo and pure in- digo as well, which is why its dye is purplish-blue. About twenty years ago, Otto Elsner from the Shenkar College of Fibers in Tel Aviv, serendipetously solved the riddle of the tekhelet color. Elsner was researching the methods used by ancient dyers and noticed that while on cloudy days Trun- culus dye tended towards purple, on sunny days it was pure blue. The dyes dibromoindigo and indigo are vat dyes, and in order for them to bind tightly to wool, they must first be reduced. Elsner and his colleague Ehud Spanier from Haifa University found that while dibromoindigo is in its reduced state, if it is exposed to ultraviolet light it will deter- mine to pure indigo. Since dying is a very smelly process, it would have been natural to dye outdoors, and in the bright Mediterranean sunlight, ancient dye masters would have quickly learned how to control the color of the Trun- culus extract. (Elsner suggested a second possibility for obtaining pure blue from Trunculus - by sex separation - as the males produce primarily indigo while the females yield dibromoindigo. This assumes that the ancient mariners could tell the difference between male and female snails - not a trivial feat since the Trunculus species is hermaphrodite, or imposexual to be more precise, with many females growing male sexual organs during their lifetime. Recent research has cast some doubt as to the statistical significance of sex as a factor in dye type, but Elsner maintains that a difference does exist.) When the dibromoindigo is completely determined to indigo there is no way of telling it from the identical indigo molecule of vegetable origin - kala ilan - as the Talmud states. Does this mean that one could today use synthetic indigo in place of the hilazon based chemical? Most Jewish legal authorities rule not. As is often the case with ritual objects, the source and process are as important as the product. Jewish mystical tradition associates the sun with God's fiery attribute of justice and the sea with His ten- dency towards kindness. To the ancient Jews of Palestine, tekhelet may have symbolized the mixture of the two; as the sea and sunlight come together to form the blue dye, so too man survives only through the mixture of both sides of God's personality. The chemicals needed for the dying process were all available to the ancients. They probably obtained potassium hydroxide (2KOH), the strong base necessary to reduce the dyes by burning sea shells (CaCO3) and mixing the result with potash (K2CO3). CaCO3 -> CaO + CO2 CaO + H2O -> Ca(OH)2 Ca(OH)2 + K2CO3 -> CaCO3 + 2KOH This provides the answer to another archeological mystery, why ovens were found at the site of the ancient dye houses. These must have been used to burn the shells in order to procure the potassium hydroxide. Over the last few decades, much work has been done to reestablish the tekhelet dying process. Irving Ziderman, from the Israel Fiber Institute has published a number of articles describing the scientific aspects and religious im- plications of the Trunculus dye. Rabbi Herzog's doctorate has finally been published after nearly 80 years. Rabbi Eliahu Tebger of Jerusalem was the first to actually apply the process according to the prescribed ritual from beginning to end, and prayer shawls - tallitot - with authentic tekhelet can be found in Jerusalem today for the first time in more than 1300 years. ----------------------------------------------------------------------
End of Volume 8 Issue 12